Concept Test 7

Internet Concept Test Chemistry 22
Prof. J. C. Baird
Marn-Yee Lee, Silvia Georges, Derek Cummings

Topic: Chemistry in the Atmosphere

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Up to 4 people can work together on this test.

There are N questions.

Background material. It is not necessary to read this, but it is pretty interesting!


Question 1

On the Internet at Indiana State University in AST-473 Upper Air Weather Dynamics it was stated: "Estmated temperatures [at 55 miles are] as high as 1370C however, due to the very thin air, the lack of molecular activity results in temperature being much colder than that found at the Earth's surface." On the face of it this statement is:

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Question 2

If the temperature of the atmosphere drops with height above the earth how is it that there is a temperature inversion (a higher temperature) in the neighborhood of 20-50 kilometers?

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Question 3

It is said that the temperature in the stratosphere is 950C at an altitude of 300Km.

If you were to stick your hand out a window of the space shuttle at that altitude, after the great sucking sound, would your hand feel hot or cold-assuming you still had any feeling left? In other words, what is meant by the temperature of the thermosphere?

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Question 4

The sun radiates energy like a blackbody at a temperature of 5783K. The distribution of radiation at the top of the atmosphere is shown in the figure below. If we express the radiation from the sun in units of kilojoules per mole the radiation is predominatly in the energy range from 60 Kj/mol (2000 nanometers) to 600 Kj/mol (200 nm). For a table of energy conversion factors click here.

The following table show the energies of dissociation of a number of molecules. Which molecules will be affected by solar radiation? Check all that apply.

Molecule Dissociation Energy Kj/mol Process
Nitrogen 1171 N_2 -> N + N
Oxygen 490.1 O_2 -> O + O
Ozone 100 O_3 -> O_2 + O
Nitric Oxide 626.8 NO -> N + O
Hydroxyl Radical 419.7 OH -> H + O
CO 881.9 CO -> C + O
CO_2 531.1 CO_2 -> C0 + O
H_2O 491.4 H_2O -> H + OH

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